Journal of Fluorine Chemistry p. 109 - 116 (1994)
Update date:2022-08-31
Topics:
Winter, Rolf
Gard, Gary L.
The addition of either SF5Br or SF5Cl to a number of unsaturated esters is discussed.The new SF5 esters, SF5CH2CHBr(OAc), SF5CH2CHBrC(O)OC2H5, SF5CH(C(O)OC2H5)CHBr(OAc) and SF5CH2CHClCH2OAc, were prepared from vinyl acetate, ethyl acrylate, β-acetoxyethyl acrylate and allyl acetate, respectively (OAc=CH3C(O)O).The ester SF5CH2C(O)OCH3 was prepared by peracid oxidation of the acetal SF5CH2CH(OCH3)2.Base treatment of SF5CH2CHClCH2OAc did not give an epoxide but, unexpectedly, produced the novel SF5CH=CHCH2OH.This alcohol is the first example of an SF5-containing ene-ol.
View More
Chengdu Baishixing Science and Technology Industry Co., Ltd.
website:http://www.cd-bsx.com
Contact:+86-28-88531548
Address:#217,North of Industry Road,Heshan Town,Pujiang County,Chengdu,Sichuan,China.
Nanjing lanbai chemical Co.,Ltd.
Contact:+86-25-85499326
Address:Room 908, 9F Taiyue Building,No.285 Heyan Road
Yantai Derun Liquid Crystal Materials Co. Ltd.
website:http://www.ytderun.com
Contact:86-535-6300169
Address:ROOM 90, XIANGFU STREET, FUSHAN NEW-HIGH-TECH IDUSTRY ZONE, YANTAI
Beyond Pharmaceutical Co., Ltd
Contact:+86-571-8195-3185
Address:No. 13-1, Liansheng Road, Yuhang District
Shandong Hongxiang Zinc Co., Ltd
Contact:086-0311-66187879
Address:DaWang developing zone
Doi:10.1007/BF00953350
(1986)Doi:10.1021/acs.cgd.8b01742
(2019)Doi:10.1021/ma201009n
(2011)Doi:10.1021/ja00323a062
(1984)Doi:10.1039/b313738d
(2004)Doi:10.1016/j.cattod.2016.01.053
(2016)
