Synthesis and application of new chiral ligands for the asymmetric borane reduction of prochiral ketones

DOI: 10.1016/0957-4166(96)00154-1

Source and publish data:

Tetrahedron Asymmetry p. 1373 - 1384 (1996)

Update date:2022-08-11

Topics:

Authors:

Hulst, Ron

Heres, Hero

Peper, Nathalie C.M.W.

Kellogg, Richard M.

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Article abstract of DOI:10.1016/0957-4166(96)00154-1

Two chiral nonracemic γ-amino alcohols, ephedrine thiol and the corresponding (thio)-phosphoramidates and (thio)-phosphinamides have been examined as catalysts for the reduction of propiophenone by various boranes. Up to 95% e.e. can be obtained with the

Full text of DOI:10.1016/0957-4166(96)00154-1

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