A Novel Intramolecular Silyl Nitronate Cycloaddition Route to Dihydrofuraldehydes and Dihydropyranaldehydes

DOI: 10.1021/jo00093a009

Source and publish data:

Journal of Organic Chemistry p. 3783 - 3785 (1994)

Update date:2022-08-03

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Authors:

Duffy, Jetty L.

Kurth, Mark J.

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Article abstract of DOI:10.1021/jo00093a009

The novel transformation (1 -> 3) of propargylic or homopropargylic nitroethers to dihydrofuraldehydes (n=0) or dihydropyranaldehydes (n=1) is reported.The transformation proceeds by a silyl nitronate olefin cycloaddition to an N-<(trimethylsilyl)oxy>isox

Full text of DOI:10.1021/jo00093a009

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