Chemistry Letters p. 859 - 860 (1995)
Update date:2022-08-28
Topics:
Hamasaki, Keita
Ueno, Akihiko
Imidazole-appended β-cyclodextrins, 3-deoxy-3=imidazolyl-β-cyclodextrin (3Im-βCyD) and 6-deoxy-6-imidazolyl-β-cyclodextrin (6Im-βCyD) were synthesized as substrate selective enzyme mimics. 6Im-βCyD shows marked enantioselectivity in the hydrolysis of Boc-alanine p-nitrophenyl ester rather than 3Im-βCyD.This selectivity could be interpreted by transition stability theory.
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