Journal of the Chemical Society. Chemical communications p. 534 - 535 (1982)
Update date:2022-08-11
Topics:
Burdon, James
Childs, Ann C.
Parsons, Ian W.
Tatlow, John Colin
Decafluoroanthracene undergoes replacement of the 2-fluorine when treated with sodium methoxide or with dimethylamine, and this is not in accord with the amplified I?-repulsion theory which requires attack at the 9-position; there is now no theory which rationalizes the position of nucleophilic replacement in all polyfluoro-aromatic compounds.
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