
Journal of the Chemical Society. Chemical communications p. 410 - 411 (1985)
Update date:2022-08-11
Topics:
Smith, John R. Lindsay
Mortimer, David N.
Replacing the tetraphenylporphyrinatoiron(III) chloride (Fe(III)TPPCl) catalyst, in Groves' model system (Fe(III)TPPCl-PhIO) for cytochrome P450 mono-oxygenases, with tetra(4-N-methylpyridyl)porphyrinatoiron(III) pentacation allows oxidations to be carried out in protic and dipolar aprotic solvents without significantly altering the mechanisms of the reactions.
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