The Oxidation of Organic Compounds with Iodosylbenzene catalysed by Tetra(4-N-methylpyridyl)porphyrinatoiron(III) Pentacation: A Polar Model System for the Cytochrome P450 Dependent Mono-oxygenases

DOI: 10.1039/c39850000410

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 410 - 411 (1985)

Update date:2022-08-11

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Authors:

Smith, John R. Lindsay

Mortimer, David N.

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Article abstract of DOI:10.1039/c39850000410

Replacing the tetraphenylporphyrinatoiron(III) chloride (Fe(III)TPPCl) catalyst, in Groves' model system (Fe(III)TPPCl-PhIO) for cytochrome P450 mono-oxygenases, with tetra(4-N-methylpyridyl)porphyrinatoiron(III) pentacation allows oxidations to be carried out in protic and dipolar aprotic solvents without significantly altering the mechanisms of the reactions.

Full text of DOI:10.1039/c39850000410

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