Tetrahedron Letters p. 5291 - 5294 (1982)
Update date:2022-08-29
Topics:
Dietrich-Buchecker, C. O.
Marnot, P. A.
Sauvage, J. P.
The reaction of an alkyl- or aryl-lithium with 1,10-phenanthroline followed by hydrolysis and rearomatisation with manganese dioxide gives good yields of the 2,9-disubstituted product.This synthetic method has been extended to other polyimines such as 2,2'-bipyridine, 2,2',6',2''-terpyridine and 1,8-naphtyridine.
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