Journal of Organic Chemistry p. 7185 - 7187 (1994)
Update date:2022-08-16
Topics:
Allen, Annette D.
Colomvakos, Jim D.
Tee, Oswald S.
Tidwell, Thomas T.
9-(Trifluoromethyl)fluorenyl tosylate (5) undergoes solvolysis to the corresponding carbocation 3, which is destabilized both by the electron-withdrawing CF3 group and by its potentially antiaromatic fluorenyl cation character.
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(1910)