Journal of Chemical Physics p. 6808 - 6815 (1986)
Update date:2022-08-11
Topics:
Konuk, Rengin
Cornelisse, J.
McGlynn, S. P.
The photoinization of 9-phenylanthracene (PhA) and the role of the radical cation in the photocyanation reaction is reported.Radical cations are produced by two processes: (a) biphotonic unimolecular ionization under high intensity laser excitation and (b) a monophotonic bimolecular electron-transfer process in the presence of dicyanobenzene (DCB) .In both cases, the singlet excited state is the precursor to the radical cation.
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