Reactions of Oxygenated Radicals in the Gas Phase. Part 5. Reactions of Methylperoxyl Radicals and Alkenes

DOI: 10.1039/P29800000065

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 65 - 67 (1980)

Update date:2022-08-11

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Authors:

Selby, Keith

Waddington, David J.

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Article abstract of DOI:10.1039/P29800000065

The reactions of methylperoxyl radicals with alkenes have been studied at 410 K.The peroxyl radicals were generated by the oxidation of methyl radicals formed during the thermal oxidation of di-t-butyl peroxide.Rate constants for reaction (18) have been determined: k₍₁₈₎(ethylene) = 1.2+/-0.7 and k₍₁₈₎(2-methylpropene) = 9.8 +/- 1.6 dm³ mol^-1s^-1 at 410 K.CH3O2^. + >C=C< <*> +/- CH3O^. (18) An estimate for an activation energy of the abstraction reaction between t-butoxyl radicals and 2-methylpropene is given.

Full text of DOI:10.1039/P29800000065

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