Journal of the Chemical Society. Perkin transactions II p. 65 - 67 (1980)
Update date:2022-08-11
Topics:
Selby, Keith
Waddington, David J.
The reactions of methylperoxyl radicals with alkenes have been studied at 410 K.The peroxyl radicals were generated by the oxidation of methyl radicals formed during the thermal oxidation of di-t-butyl peroxide.Rate constants for reaction (18) have been determined: k(18)(ethylene) = 1.2+/-0.7 and k(18)(2-methylpropene) = 9.8 +/- 1.6 dm3 mol-1s-1 at 410 K.CH3O2. + >C=C< <*>
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