Reactions of Oxygenated Radicals in the Gas Phase. Part 5. Reactions of Methylperoxyl Radicals and Alkenes

DOI: 10.1039/P29800000065

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 65 - 67 (1980)

Update date:2022-08-11

Topics:

Authors:

Selby, Keith

Waddington, David J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P29800000065

The reactions of methylperoxyl radicals with alkenes have been studied at 410 K.The peroxyl radicals were generated by the oxidation of methyl radicals formed during the thermal oxidation of di-t-butyl peroxide.Rate constants for reaction (18) have been determined: k₍₁₈₎(ethylene) = 1.2+/-0.7 and k₍₁₈₎(2-methylpropene) = 9.8 +/- 1.6 dm³ mol^-1s^-1 at 410 K.CH3O2^. + >C=C< <*> +/- CH3O^. (18) An estimate for an activation energy of the abstraction reaction between t-butoxyl radicals and 2-methylpropene is given.

Full text of DOI:10.1039/P29800000065

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(+)-propylene oxide

Cas No:16033-71-9

R&D Labs maybe for 16033-71-9

Shandong united-rising pharmaceutical cooperation.,ltd.

Contact:008653187965009

Address:171No., Jing5 Road, Shizhong District, Jinan, China
KODI CHEMICAL CO., LTD

Contact:021

Address:Pudong
Beijing Mediking Biopharm Co., Ltd.

Contact:+86-10-89753524/81760121/81769521

Address:Hongxianghong Incubator, Beiqijia Town, Changping district, Beijing, China
Heliosense Biotechnologies, Inc.

Contact:+86-592-5667290

Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506
HAINAN JINYING IMPORT AND EXPORT CO. LTD

Contact:+86-898-32875423

Address:A SECTION 19TH FL, TIMES SQUARE, NO.2 GUO MAO AVENUE HAIKOU, HAINAN, P. R. OF CHINA

Relevant to this article

Aziridination of Alkenes using 3-Acetoxyaminoquinazolin-4-(3H)ones in the Presence of Tertiary Amines: Evidence for an Azaimide (N-Nitrene) Intermediate

Doi:10.1039/c39950000819
(1995)
Synthesis of new telechelic polymers containing two OH groups at the same chain end using 8-boraindane/oxygen controlled radical initiator

Doi:10.1021/ma0495341
(2004)
Cluster expansion reactions of group 6 and 8 metallaboranes using transition metal carbonyl compounds of groups 7-9

Doi:10.1021/ic200802c
(2011)
Multicomponent approach to silica-grafted peptide catalysts: A 3D continuous-flow organocatalytic system with on-line monitoring of conversion and stereoselectivity

Doi:10.1002/cctc.201402501
(2014)
An investigation on the two-photon absorption activity of various terpyridines and related homoleptic and heteroleptic cationic Zn(II) complexes

Doi:10.1039/b515129e
(2006)
Doi:10.1021/ja01219a512
(1945)

Article Doi