PHOTOCHEMISTRY OF BRIDGED CYCLOHEPTADIENES. MULTIPLICITY DEPENDENT PERICYCLIC REARRENGEMENTS OF EXCITED BICYCLONONA-2,4-DIENE-7,7,8,8-TETRACARBONITRILE

DOI: 10.1016/S0040-4039(00)96647-4

Source and publish data:

Tetrahedron Letters p. 4867 - 4870 (1987)

Update date:2022-08-02

Topics:

Authors:

Goldschmidt, Zeev

Genizi, Elisheva

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Article abstract of DOI:10.1016/S0040-4039(00)96647-4

Bicyclo<4.2.1>nona-2,4-diene-7,7,8,8-tetracarbonitrile rearranges selectively under direct irradiation in acetonitrile to tricyclo<3.2.2.0^2,4>non-6-ene-8,8,9,9-tetracarbonitrile, and upon acetone sensitization to bicyclo<3.2.2>nona-2,6-diene-8,8,9,9-tetracarbonitrile.Both products are derived from sigma bond cleavage, in contrast to the parent unsubstituted diene where only the ?-bonds react.

Full text of DOI:10.1016/S0040-4039(00)96647-4

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Product name:tricyclo<3.2.2.0^2,4>non-6-ene-8,8,9,9-tetracarbonitrile

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