Formation of 9,25-cyclofernane by reductive homoallylic cyclization of fern-9(11)-en-25-ol mesylate

DOI: 10.1248/cpb.42.1334

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1334 - 1335 (1994)

Update date:2022-08-17

Topics:

Authors:

Fujimoto

Murasaki

Eguchi Eguchi

Kakinuma

Dutta Dutta

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Article abstract of DOI:10.1248/cpb.42.1334

Treatment of fern-9(11)-en-25-ol mesylate (2) with LiAlH₄ in refluxing tetrahydrofuran afforded 9,25-cyclofernane (4), a new cyclopropane ring- containing triterpene, in a moderate yield.

Full text of DOI:10.1248/cpb.42.1334

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Product name:FERN-9(11)-ENE

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