Journal of Organometallic Chemistry p. C44 - C46 (1986)
Update date:2022-08-17
Topics:
Kikukawa, Kiyoshi
Umekawa, Hideto
Matsuda, Tsutomu
Under palladium(0) catalysis, Ph(R3Sn)C=CH2 (R=Me, Et and Bu) easily reacted with ArN2BF4 (Ar=XPh, X=H, 4-Me, 4-I, 4-MeCO, 4-EtOCO, 3-NO2 and 4-NO2) and selectively produced (Z)-PhCH=CHAr but not Ph(Ar)C=CH2.An addition-elimination mechanism instead of the transmetallation from tin to palladium is postulated for this unusual regiochemistry.
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