THE MECHANISM OF THE REACTION OF ARYLOXYTRIMETHYLSTANNANE WITH METHANESULFONYL CHLORIDE

DOI: 10.1246/cl.1981.1299

Source and publish data:

Chemistry Letters p. 1299 - 1300 (1981)

Update date:2022-08-17

Topics:

Authors:

Kozuka, Seizi

Yamaguchi, Shigeru

Tagaki, Waichiro

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Article abstract of DOI:10.1246/cl.1981.1299

A kinetic study has been conducted for the reaction of aryloxytrimethylstannane with methanesulfonyl chloride.Substituent effect was found to be dependent on the solvent and obscure solvent effect was observed.A mechanism has been suggested involving nearly concerted four-center transition state.

Full text of DOI:10.1246/cl.1981.1299

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