EFFICIENT PREPARATION OF ALLYLIC GRIGNARD REAGENTS USING SLURRIES OF PRECONDENSED MAGNESIUM

DOI: 10.1016/S0040-4039(00)87738-2

Source and publish data:

Tetrahedron Letters p. 3901 - 3904 (1982)

Update date:2022-08-11

Topics:

Authors:

Oppolzer, Wolfgang

Kuendig, Ernest Peter

Bishop, Paul M.

Perret, Celia

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Article abstract of DOI:10.1016/S0040-4039(00)87738-2

Using a simple apparatus addition of 2-alkenyl halides to precondensed active Mg in THF gave clean solutions of 2-alkenylmagnesium halides which on carbonation furnished β,γ-unsaturated carboxylic acid in high yields.

Full text of DOI:10.1016/S0040-4039(00)87738-2

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