Tetrahedron Letters p. 1513 - 1516 (1998)
Update date:2022-08-11
Topics:
Gravert, Dennis J.
Janda, Kim D.
Novel bifunctional initiators have been designed with functional groups that independently produce free radicals. Initiators were synthesized to contain both diazene (-N=N-) and 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) moieties tethered by ester or ether linkages. It is anticipated that these compounds will be useful for producing a diverse number of block copolymers for applications in polymer-supported organic synthesis and materials science.
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