Formation of Dithioacetals by Treatment of Sulfoxides Carrying α-Hydrogens with Magnesium Amides

DOI: 10.1246/cl.1994.1551

Source and publish data:

Chemistry Letters p. 1551 - 1554 (1994)

Update date:2022-08-17

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Authors:

Kobayashi, Kazuhiro

Kawakita, Masataka

Mannami, Tohru

Morikawa, Osamu

Konishi, Hisatoshi

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Article abstract of DOI:10.1246/cl.1994.1551

Sulfoxides carrying α-hydrogens were allowed to react with magnesium amides generated in situ by the treatment of ethylmagnesium bromide with secondary amines such as 2,2,6,6-tetramethylpiperidine or diisopropylamine in diethyl ether to give the corresponding dithioacetals in moderate to good yields.

Full text of DOI:10.1246/cl.1994.1551

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