INFLUENCE OF THE CHEMICAL AND TEXTURAL PORPERTIES OF K2Cr2O7 SUPPORTED ON SOLIDS, IN THE OXIDATION OF CHOLESTEROL

DOI: 10.1016/S0040-4020(01)90299-6

Source and publish data:

Tetrahedron p. 3303 - 3308 (1987)

Update date:2022-08-16

Topics:

Authors:

Climent, M. S.

Marinas, J. M.

Sinisterra, J. V.

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Article abstract of DOI:10.1016/S0040-4020(01)90299-6

Several K2Cr2O7 supported reagents on inert solids have been obtained by deposition of K2Cr2O7 on different solids.AlPO, BPO and solid mixtures BPO-AlPO are used as supports.The K2Cr2O7 is deposited on solid as large crystals detected by an X-ray diagram in the Cr50 and Cr25 series giving solids with very low surface areas.The number of acid and oxidizing sites is determined.Solids supports with small surface areas and large pore diameter give K2Cr2O7 supported reagents with higher activity than those obtained from solids with high surface areas and large pores.

Full text of DOI:10.1016/S0040-4020(01)90299-6

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