Chemistry Letters p. 83 - 86 (1989)
Update date:2022-08-17
Topics:
Nakano, Taichi
Nakamura, Hidehisa
Nagai, Yoichiro
The Cp2TiPh2-catalyzed reaction of dihydrosilanes afforded dehydrogenative coupling products, disilanes and/or trisilanes.The reaction using phenylsilane produced hydride-terminated poly(phenylsilylene) polymers with Mn=730 and Mw=960, which exhibited the longest UV absorption maximum at 245 nm (ε, 5.7x104).
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