
Journal of the Chemical Society. Chemical communications p. 684 - 685 (1982)
Update date:2022-08-10
Topics:
Issari, Bahram
Stirling, Charles J. M.
Ranks (<*> nucleofugalities) of Br, Cl, OSO2C6H4Me, SO2Ph, SPh, and OPh as leaving groups in sulphonylactivated cyclopropane-forming eliminations have been determined; a rectilinear correlation between rank and the pKa of the conjugate acid of the leaving group is found in direct contrast with behaviour in alkene-forming elimination.
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