Tetrahedron Letters p. 6319 - 6322 (1989)
Update date:2022-08-11
Topics:
Sage, Jean-Marc
Gore, Jacques
Guilmet, Elisabeth
Selective oxidation of a terminal olefin by a mixed catalytic system comprising Pd(dba)2 and silver nitrite gives a methyl ketone.A WACKER type mechanism is proposed, in which organic nitrites derives from the alcoholic solvent used are involved.
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