Journal of Organic Chemistry p. 5495 - 5499 (1985)
Update date:2022-08-11
Topics:
Goering, Harlan L.
Kantner, Steven S.
Seitz, Earl P.
Relative rates of reaction of 19 allylic esters with LiCuMe2 in ether have been determined by a competitive reaction technique.The reactivity range for the series is >3*105.The relationship between structure and reactivity is compatible with a rate-limiting SN2' oxidative addition to give a ?-allyl copper(III) complex.
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(1970)
