Mechanistic studies on the diastereoselectie halohydroxylation of γ-δ unsaturated carboxamides

DOI: 10.1016/0040-4039(96)01529-8

Source and publish data:

Tetrahedron Letters p. 6843 - 6846 (1996)

Update date:2022-08-16

Topics:

Authors:

Rossen Rossen

Reamer Reamer

Volante Volante

Reider Reider

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Article abstract of DOI:10.1016/0040-4039(96)01529-8

Evidence is presented that the diastereoselective iodohydroxylation of the γ-δ unsaturated amide 2 proceeds without involvement of iminium ion 12 directly to the tetrahedal intermediate 17 and its subsequent endocyclic cleavage to 3.

Full text of DOI:10.1016/0040-4039(96)01529-8

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