Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 557 - 561 (1991)
Update date:2022-08-11
Topics:
Ivanova, N. M.
Cheskis, B. A.
Rubanova, E. V.
Yatsynin, V. G.
Moiseenkov, A. M.
Nefedov, O. M.
Stereospecific synthesis of the linear E-olefins mentioned in the title was realized by a general scheme that was worked out earlier by the authors and which includes as key step homologization of the corresponding aliphatic pentakisnoraldehydes by means of trimethylsilyloxyvinylcyclopropane and ZnBr2-initiated rearrangement of the intermediate cyclopropylcarbinols under the influence of Me3SiBr.
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