NEW SYNTHETIC "TRICKS". (Et3NH)(Sn(SPh)3) AND Bu2SnH2, TWO USEFUL REAGENTS FOR THE REDUCTION OF AZIDES TO AMINES

DOI: 10.1016/S0040-4039(01)81096-0

Source and publish data:

Tetrahedron Letters p. 5941 - 5944 (1987)

Update date:2022-08-04

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Authors:

Bartra, Marti

Urpi, Felix

Vilarrasa, Jaume

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Article abstract of DOI:10.1016/S0040-4039(01)81096-0

Treatment of Sn(SPh)2 with PhSH and Et3N affords a tin(II) complex, soluble in organic solvents, wich is the best reducing agent for azides reported so far.Bu2SnH2, although not so reactive, also shows several advantages with regard to the standard reducing agents for azides, such as its solubility in most solvents or its scarce reactivity with water.

Full text of DOI:10.1016/S0040-4039(01)81096-0

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