Synthesis and properties of poly(2-methoxy-5-propagyloxy-1, 4-phenylenevinylene)

Article abstract of DOI:10.1080/10587259608040328

New PPV derivatives containing cross-linkable acetylene groups, poly(2-methoxy-5-propagyloxy-l,4-phenylenevinylene) (PMPPV) and its PPV copolymers were synthesized through the soluble precursor polymers. PMPPV film was higly cross-linked and lost its properties of a conjugated polymer at over 200 °C. The electrical conductivities of PMPPV films were measured by four probe method after FeCl₃ doping. The undrawn and 10 times drawn PMPPV films showed thier electrical conductivities of 1.5 × 10^-1 and 92 S/cm, respectively. Conjugation length of poly(PV-co-MPPV) was controlled by changing the PMPPV monomer feed ratio.

Full text of DOI:10.1080/10587259608040328

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Molecular Crystals and Liquid Crystals
Science and Technology. Section A.
Molecular Crystals and Liquid Crystals
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Synthesis and Properties of Poly(2-
Methoxy-5-Propagyl-Oxy-1,4-
Phenylenevinylene)
a
a
a
Do-Hoon Hwang , Chong-Bok Yoon , Ki-Jeong Moon & Hong-
a
Ku Shim
a
Department of Chemistry , Korea Advanced Institute of Science
and Technology , Taejon, 305-701, Korea
Published online: 04 Oct 2006.
To cite this article: Do-Hoon Hwang , Chong-Bok Yoon , Ki-Jeong Moon & Hong-Ku Shim (1996)
Synthesis and Properties of Poly(2-Methoxy-5-Propagyl-Oxy-1,4-Phenylenevinylene), Molecular
Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid
Crystals, 280:1, 175-180, DOI: 10.1080/10587259608040328
To link to this article: http://dx.doi.org/10.1080/10587259608040328
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