Chemistry Letters p. 1393 - 1396 (1993)
Update date:2022-08-28
Topics:
Yasui, Shinro
Shioji, Kosei
Ohno, Atsuyoshi
Yoshihara, Masakuni
Photo-redox between diphenylphosphine oxide and 10-methylacridinium iodide with visible light in aqueous acetonitrile under argon atmosphere is initiated by single electron transfer from the phosphorus compound to the acridinium salt in the potoexcited state giving diphenylphosphinic acid and 10-methylacridan as the final products.Iodide ion/iodine couple plays a crucial role for transferring an electron in this reaction.
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