Asymmetric hydrogenation of α,β-unsaturated carboxylic acids in supercritical carbon dioxide

DOI: 10.1016/0040-4039(96)00436-4

Source and publish data:

Tetrahedron Letters p. 2813 - 2816 (1996)

Update date:2022-08-11

Topics:

Authors:

Xiao, Jianliang

Nefkens, Sylvia C. A.

Jessop, Philip G.

Ikariya, Takao

Noyori, Ryoji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)00436-4

Hydrogenation of tiglic acid in supercritical CO₂ catalyzed by a chiral H₈-BINAP-Ru(II) complex proceeds cleanly with cis stereochemistry to afford 2-methylbutanoic acid in up to 89% ee and over 99% yield.

Full text of DOI:10.1016/0040-4039(96)00436-4

Products guided by the article

Product name:(S)-(+)-2-Methylbutyric acid

Cas No:1730-91-2

R&D Labs maybe for 1730-91-2

Rayfull Holding Co., Ltd

Contact:+86-577-65618087-605

Address:Room 402, Unit 4 Xinhu Bldg. Waitan Ruian City, Zhejiang China.
SPRING CHEMICAL INDUSTRY CO.,LTD

Contact:86-187-66672125

Address:linchi industry park.zouping
Beijing Wisdom Chemicals Co., Ltd.

Contact:+86-10-52350335

Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD

website:http://www.czyys.com

Contact:0086-519-88802789

Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307

Relevant to this article

Electron delocalization in vinyl ruthenium substituted cyclophanes: Assessment of the through-space and the through-bond pathways

Doi:10.1016/j.jorganchem.2011.06.028
(2011)
The preparation and crystal structures of the compounds (Ph2MeSi)3CMCl (M=Zn, Cd, or Hg)

Doi:10.1016/0022-328X(93)83340-2
(1993)
Kinetic resolution and asymmetric oxidation as combined routes to chiral sulfoxides

Doi:10.1016/S0957-4166(97)00268-1
(1997)
Bismuth subnitrate catalyzed efficient synthesis of 3,4-dihydropyrimidin- 2(1H)-ones: An improved protocol for the Biginelli reaction

Doi:10.1081/SCC-200032533
(2004)
Synthesis of C-mannopyranosylphloroacetophenone derivatives and their anomerization

Doi:10.1016/S0008-6215(01)00076-3
(2001)
Rh-Ni/MgAl₂O₄ catalyst for steam reforming of methane: Effect of Rh doping, calcination temperature and its application on metal monoliths

Doi:10.1016/j.apcata.2018.11.021
(2019)

Article Doi