Fluorination or hydroxylation of non activated C-H bonds in amides and ketones using CCl4 or NBS in superacids

DOI: 10.1016/0040-4039(96)00475-3

Source and publish data:

Tetrahedron Letters p. 2967 - 2970 (1996)

Update date:2022-08-10

Topics:

Authors:

Martin, Agnes

Jouannetaud, Marie-Paule

Jacquesy, Jean-Claude

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)00475-3

Amides and ketones are fluorinated or hydroxylated in HF-SbF₅ in the presence of CCl₄ or NBS, reaction occurring at a carbon far located from the functional group.

Full text of DOI:10.1016/0040-4039(96)00475-3

Products guided by the article

Product name:Cyclohexanone, 4-(1-hydroxy-1-methylethyl)-

Cas No:17328-67-5

R&D Labs maybe for 17328-67-5

AstaTech ( Chengdu) BioPharmaceutical Corp.

website:http://www.astabiochem.cn/

Contact:+86-15198215156-15198215156

Address:SICHUAN CHENGDU
Wuhan Silworld Chemical Co.,Ltd

website:http://www.silworldchemical.com

Contact:+86-27-85613400

Address:No.198 jiangjun Road, Wuhan,China 430033
Zhejiang Newfine Industry Co.,Ltd.

Contact:+86-573-82262042

Address:No.225,Dongqing Road, garoms@163.com
Josun International Limited

website:http://www.josunpharma.com

Contact:+86-311-80715268 80766839

Address:No.39, Zhaiying Street, Shijaizhuang,Hebei,China
Daqing E-shine Chemical Co.,LTD

Contact:0086-024-31285112

Address:Hongweiyuan area, Ranghulu district

Relevant to this article

Doi:10.1021/ja01549a053
(1958)
Discovery and in Vivo Anti-inflammatory Activity Evaluation of a Novel Non-peptidyl Non-covalent Cathepsin C Inhibitor

Doi:10.1021/acs.jmedchem.1c00104
(2021)
A new simple and high-yield synthesis of 5α-dihydrotestosterone (DHT), a potent androgen receptor agonist

Doi:10.1016/j.steroids.2012.09.003
(2012)
Electron Transfer between Cytochrome c and Porphyrins

Doi:10.1021/ja00271a005
(1986)
Pentacyclo<4.3.1.0^1,6.0^7,9.0^8,10>decane: A Cyclopropane Edge-Bridged Prismane and Its Rearrangement to a Fulvene

Doi:10.1021/ja00243a066
(1987)
Synthesis of the First Homoleptic Trisilaallyl Chloride: 3-Chloro-1, 1,2, 3,3-pentakis(2′,4′,6′-triisopropylphenyl)trisil-1-ene: 3-Chloro-1

Doi:10.1002/zaac.201500561
(2015)

Article Doi