Journal of Fluorine Chemistry p. 133 - 140 (1993)
Update date:2022-08-11
Topics:
Puy, Michael Van Der
1,1,1-Trichlorotrifluoroethane was added to seven different olefins using a redox system, giving adducts having the CF3CCl2-C-CCl- subunit.Selective addition to the exocyclic double bond in limonene was observed.The adducts were dechlorinated by catalytic reduction or with tri-n-butyltin hydride.The two-step sequence thus provided a method for appending the trifluoroethyl group (CF3CH2-) to olefins.
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