Bulletin of the Chemical Society of Japan p. 1855 - 1856 (1983)
Update date:2022-08-16
Topics:
Singh, Sukham Nabakishwar
Bhattacharjee, Mitra
Mahanti, Mahendra Kumar
The reaction between guaiacol and alkaline hexacyanoferrate(III), at constant ionic strength, gave a coupled product, 3:3'-dimethoxydiphenoquinone.The rate of the reaction was dependent on the first orders of the concentrations of substrate, oxidant, and alkali.The rate determining step involved the formation of a radical intermediate, which was detected by ESR spectroscopy.
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