Journal of Fluorine Chemistry p. 219 - 232 (1984)
Update date:2022-08-11
Topics:
Frohn, Hermann Josef
Pahlmann, Wolfgang
The behavior of iodine pentafluoride towards nucleophilic exchange of fluoride against monofunctional alcoholates in aprotic media is investigated using silylated methanol, isopropanol, tertiary butanol, phenol, alkylated phenol, and pentachlorophenol as educts. 19F-NMR-spectroscopic and preparative details are given for iodine(V)-fluoride-methanolates and fluoride-oxides.Dismutation, elimination,and redox reactions involving iodine(V)-alkoxide and aryloxide-fluorides are reported.
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