Chemistry Letters p. 269 - 272 (1987)
Update date:2022-08-17
Topics:
Kambe, Nobuaki
Tsukamoto, Takashi
Miyoshi, Noritaka
Murai, Shinji
Sonoda, Noboru
Olefins were found to be oxidized by use of benzenetellurinic anhydride in acetic acid leading to vic-diacetates.Benzenetellurenic acid derivatives formed in situ are suggested as the active species.This diacetoxylation proceeds in net syn fashion probably via anti acetoxytellurenylation of the olefin followed by displacement of the phenyltelluro group by an acetoxy group with inversion.
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