Oxygen-functionalization of C13-angular methyl group in pregnane steroid by means of intramolecular carbony-mediated anodic oxidation

DOI: 10.1248/cpb.40.1143

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1143 - 1147 (1992)

Update date:2022-08-11

Topics:

Authors:

Shibuya Shibuya

Murakami

Shimada Shimada

Yoshikawa

Kitagawa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.40.1143

An oxygen-functionalization of the C₁₃-angular methyl group in 3β-acetoxy-5α-pregnan-20-one and its tetra-O-acetyl-β-D-glucopyranosyl derivative has been effected by means of an anodic oxidation mediated by the C₂₀-carbonyl residue in the steroid skeleton.

Full text of DOI:10.1248/cpb.40.1143

NII-Electronic Library Service

Products guided by the article

Product name:Pregnenolone acetate

Cas No:1778-02-5

R&D Labs maybe for 1778-02-5

Reliable Pharma Technology (Shanghai) Co., Ltd.

Contact:0086-21-67676847-8008

Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.
Xi'an caijing Opto-Electrical Science & Technology Co., LTD

Contact:+86-29-88294447

Address:NO.168 Zhangba Rd. East, Xi'an, P.R.China
Chengdu Herbpurify Co., Ltd

website:http://www.herbpurify.com

Contact:0086-028-85249238

Address:Room709-C1,Incubator Building, Tianfu Life Science Park No.88,Keyuan Road,Gaoxin district,Chengdu City,Sichuan Prov,China
Santow Laboratory Limited

Contact:+86-371-55981030

Address:Room 1571, Macalline Soho, No.1, Shangdu Road, Zhengzhou, Henan
Pure Chemistry Scientific Inc.

Contact:+1-857-366-7588

Address:14905 SW freeway street #232, Sugarland, TX 77478, USA

Relevant to this article

An in situ infrared study of dimethyl carbonate synthesis from carbon dioxide and methanol over zirconia

Doi:10.1006/jcat.2001.3411
(2001)
On-water, catalyst-free and room-temperature construction of 2-aryl-1,3,4-oxadiazole derivatives from 1,1-dichloro-2-nitroethene and hydrazides

Doi:10.1039/c5ra11213c
(2015)
A new salicylic acid-derivatized kojic acid vanadyl complex: Synthesis, characterization and anti-diabetic therapeutic potential

Doi:10.1016/j.jinorgbio.2011.05.008
(2011)
Low-temperature synthesis of single crystalline Ag₂S nanowires on silver substrates

Doi:10.1021/jp050126o
(2005)
Doi:10.1139/v73-201
(1973)
Ruthenium(II)–arene and triruthenium-carbonyl cluster complexes with new water-soluble phopsphites based on glucose: Synthesis, characterization and antiproliferative activity

Doi:10.1016/j.jorganchem.2020.121312
(2020)

Article Doi