Double Silylation of Allene and Buta-1,2-diene: Formation of New Organosilicon Compounds containing both Vinylsilane and Allylsilane Units

DOI: 10.1039/c39810000617

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 617 - 618 (1981)

Update date:2022-08-11

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Authors:

Watanabe, Hamao

Saito, Masayuki

Sutou, Naotake

Nagai, Yoichiro

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Article abstract of DOI:10.1039/c39810000617

Addition of chloromethyl- and methoxymethyldisilanes, as well as hexamethyldisilane, to allene and buta-1,2-diene in the presence of a Pd(PPh3)4 catalyst gave, regioselectively, new functionalized organosilicon compounds, 2,3-bis(organosilyl)prop-1-enes and 2,3-bis(organosilyl)but-1-enes, respectively.

Full text of DOI:10.1039/c39810000617

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