The Solvolysis of N-Acetoxy-2-acetylaminofluorene and N-Acetoxy-4-acetylaminobiphenyl: Delicate Balance between Nitrenium Ion Formation and Hydrolysis

DOI: 10.1039/c39850000136

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 136 - 138 (1985)

Update date:2022-08-11

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Authors:

Underwood, Graham R.

Kirsch, Robert B.

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Article abstract of DOI:10.1039/c39850000136

The solvolysis of N-acetoxy-2-acetylaminofluorene in aqueous acetone at neutral pH proceeds exclusively with nitrenium ion formation while under the same conditions, the 4-aminobiphenyl analogue undergoes exclusive acyl-oxygen scission.

Full text of DOI:10.1039/c39850000136

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