Journal of Fluorine Chemistry p. 175 - 180 (1993)
Update date:2022-08-28
Topics:
Nishida, Masakazu
Fujii, Shozo
Kimoto, Hiroshi
Hayakawa, Yoshio
Sawada, Hideo
Cohen, Louis A.
Some silylated purines react with bis(perfluorobutyryl) peroxide to provide ring-C3F7 derivatives.The introduction of the C3F7 group occurs predominantly at C-8: 6-methoxypurine also gave the C-2 isomer in isolable yield.Replacement of the 6-amino group of adenine with dimethylamino or methoxy improved the yields of the C3F7 derivatives.
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