Photoreaction via Non-Resonant Two-Photon Excitation. Selective Silylene Extrusion from 2,2-Diphenyltrisilane

DOI: 10.1246/cl.1995.3

Source and publish data:

Chemistry Letters p. 3 - 4 (1995)

Update date:2022-08-29

Topics:

Authors:

Kira, Mitsuo

Miyazawa, Takashi

Koshihara, Shin-ya

Segawa, Yusaburo

Sakurai, Hideki

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Article abstract of DOI:10.1246/cl.1995.3

Non-resonant two-photon excitation of 2,2-diphenylhexamethyltrisilane with a 532 nm pulsed laser light induced the two major reactions, silylene extrusion and migration of the β-trimethylsilyl group with a quite different selectivity from that for the single-photon excitation.

Full text of DOI:10.1246/cl.1995.3

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