PHOTOLYSIS AND PYROLYSIS OF POLYSILYLATED DIAZOMETHANES. EFFECTIVE MIGRATING TENDENCY OF TRIMETHYLSILYL GROUP TO A CARBENE CENTER

DOI: 10.1246/cl.1983.871

Source and publish data:

Chemistry Letters p. 871 - 874 (1983)

Update date:2022-08-30

Topics:

Authors:

Sekiguchi, Akira

Ando, Wataru

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Article abstract of DOI:10.1246/cl.1983.871

Photolysis and pyrolysis of polysilylated diazomethanes were investigated, and a selective migration of trimethylsilyl group to a carbene center was observed.

Full text of DOI:10.1246/cl.1983.871

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