Cyanation of 1-Halocycloalkenes Catalyzed by Tetracyanocobaltate(I). Convenient Synthesis of 1-Cyanocycloalkenes

DOI: 10.1246/bcsj.56.649

Source and publish data:

Bulletin of the Chemical Society of Japan p. 649 - 650 (1983)

Update date:2022-08-30

Topics:

Authors:

Funabiki, Takuzo

Kishi, Hirohito

Sato, Yoshihiro

Yoshida, Satohiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.56.649

1-Cyanocycloalkenes (1-cyanocyclopentene, -hexene, -heptene, and -octene) were readily synthesized by catalytic cyanation of the corresponding 1-halocycloalkenes with tetracyanocobaltate(I).Reactivities of methyl-substituted 1-chlorocyclohexenes were lower than that of 1-chlorocyclohexene, and 1-chloro-2-methylcyclohexene scarecely reacted.Hydrogenation and isomerization of 1-cyanocycloalkenes were observed only with 1-cyanocycloheptene and 1-cyano-6-methylcyclohexene, respectively.

Full text of DOI:10.1246/bcsj.56.649

Products guided by the article

Product name:CYCLOHEXENE-1-CARBONITRILE

Cas No:1855-63-6

R&D Labs maybe for 1855-63-6

SunaTech Inc.

Contact:+86 512 6287 2180

Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
taizhou creating bio-pharm co.,ltd.

Contact:+86- 576- 88827176

Address:715 room ,unit A.junyue Building,Jiaojiang,Taizhou,Zhejiang,China
Shreeji pharma international

Contact:0091-265-2313036

Address:311, ATLANTIS HEIGHTS SARABHAI MAIN ROAD,VADIWADI ,VADODARA
TAIZHOU XINGCHENG CHEMPHARM CO.,LTD.

Contact:0086-0576-88551200,88886292 ,88880039

Address:B Area. 10 Floor.Yaodadasha. 289#.Shifu Road.Taizhou.Zhejiang.China
Huayi Isotopes Co.

Contact:+ 86 512 52491118

Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China

Relevant to this article

Sequential oxidation and condensation of alcohols to benzimidazoles/ benzodiazepines by MoO₃-SiO₂ as a heterogeneous bifunctional catalyst

Doi:10.1016/j.catcom.2010.07.008
(2010)
Synthesis and Bioactivity of Polymer-Based Synthetic Mimics of Antimicrobial Peptides (SMAMPs) Made from Asymmetrically Disubstituted Itaconates

Doi:10.1002/chem.201800907
(2018)
Synthesis of fucose derivatives with thiol motifs towards suicide inhibition of helicobacter pylori

Doi:10.3390/molecules25184281
(2020)
Novel pyrazolo[3,4-d]pyrimidine with 4-(1H-benzimidazol-2-yl)-phenylamine as broad spectrum anticancer agents: Synthesis, cell based assay, topoisomerase inhibition, DNA intercalation and bovine serum albumin studies

Doi:10.1016/j.ejmech.2016.09.093
(2017)
Rhodium(III)-Catalyzed Decarboxylative Aminomethylation of Glycine Derivatives with Indoles via C-H Activation

Doi:10.1021/acs.joc.9b03365
(2020)
Palladium-Catalyzed Direct Ortho-C-H Selenylation of Benzaldehydes Using Benzidine as a Transient Directing Group

Doi:10.1021/acs.orglett.9b02530
(2019)

Article Doi