Australian Journal of Chemistry p. 469 - 474 (1992)
Update date:2022-08-28
Topics:
Brown, Roger F. C.
Collins, David J.
Lagniton, Liana M.
Smith, Reginald J.
Wong, Neil R.
The Polonovski Reaction of castanospermine tetraacetate N-oxide with acetic anhydride gave (+/-)-1-acetoxy-8-hydroxy-2,3-dihydro-1H-indolizinium acetate (10) by aromatization of the piperidine ring.N-Bromosuccinimide oxidation of castanospermine tetraacetate gave a low yield (4percent) of (+)-2-bromo-5,6,7,8-tetrahydroindolizine-6,7,8-triyl triacetate (13), by aromatization of the pyrrolidine ring.
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