Effect of Bonded-Chain Rigidity on Selectivity in Reversed-Phase Liquid Chromatography

DOI: 10.1021/j100272a039

Source and publish data:

Journal of Physical Chemistry p. 5770 - 5772 (1985)

Update date:2022-08-16

Topics:

Authors:

Lochmueller, C.H.

Hunnicut, M.L.

Mullaney, J.F.

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Article abstract of DOI:10.1021/j100272a039

A model stationary phase has been synthesized and used to test the predictions of a lattice-model-based, unified molecular theory for selectivity in reversed-phase liquid chromatography recently proposed by Martire and Boehm.The results of the measurement of selectivity for flexible-chain, rigid-rod, and platelike solutes support the predictions of the model with selectivity following the order rods > plates > flexible chains.

Full text of DOI:10.1021/j100272a039

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