
Bulletin of the Chemical Society of Japan p. 442 - 445 (1984)
Update date:2022-08-16
Topics:
Yamaguchi, Seiji
Yamamoto, Satoru
Abe, Shoichi
Kawase, Yoshiyuki
Orientation in acylation reactions of 2,2-dimethyl-2H-chromenes was studied.Five acetylchromenes were obtained with two methods and six formylchromenes were obtained with a third method.Demethylation of four acyl-methoxy-substituted chromenes gave the corresponding acylchromenols. 2,2-Dimethyl-2H-chromene-6-carboxylic acid (anofinic acid) was also obtained by oxidation of 6-formylchromene.
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