Syntheses, structures, and reactivities of novel silacyclic systems: The first stable silabenzene and silacyclopropabenzene

Article abstract of DOI:10.1080/10426500108546528

The first stable silabenzene and silacyclopropabenzenes were synthesized by taking advantage of an efficient steric protection group, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt). The molecular geometries of these novel conjugated ring systems containing a silicon atom were definitively determined by X-ray crystallographic analysis. Their spectral data such as ¹H, ¹³C, and ²⁹Si NMR, FT-Raman, and UV-vis spectra and the theoretical calculations revealed their unique properties.

Full text of DOI:10.1080/10426500108546528

Phosphorus, Sulfur, and Silicon and the Related Elements
ISSN: 1042-6507 (Print) 1563-5325 (Online) Journal homepage: http://www.tandfonline.com/loi/gpss20
Syntheses, Structures, and Reactivities of Novel
Silacyclic Systems: the First Stable Silabenzene and
Silacyclopropabenzene
Norihiro Tokitoh
To cite this article: Norihiro Tokitoh (2001) Syntheses, Structures, and Reactivities of Novel
Silacyclic Systems: the First Stable Silabenzene and Silacyclopropabenzene, Phosphorus,
Sulfur, and Silicon and the Related Elements, 168:1, 31-40, DOI: 10.1080/10426500108546528
To link to this article: http://dx.doi.org/10.1080/10426500108546528
Published online: 02 Apr 2008.
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Date: 15 February 2016, At: 20:13