Chemistry Letters p. 671 - 674 (1989)
Update date:2022-08-12
Topics:
Setsune, Jun-ichiro
Ishimaru, Yoshihiro
Saito, Yasushi
Kitao, Teijiro
Bis(aquo)tetra(p-tolyl)porphinatocobalt(III) perchlorate reacted immediately with acetylene, in the absence and presence of tetra(p-tolyl)porphinatocobalt(II), to give a N,N'-vinylene linked bisporphyrin biscobalt(II) complex and a Co,N'-vinylene linked bisporphyrin cobalt(III) complex (4b), respectively. 4b was oxidatively converted into N,N'-vinylene linked bisporphyrin free base.An octaethylporphyrin analogue corresponding to 4b was obtained when a mixture of bis(aquo)octaethylporphyrinatocobalt(III) perchlorate and octaethylporphyrin was allowed to react with acetylene gas.
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Doi:10.1021/ja01516a069
(1959)Doi:10.1007/BF01187679
()Doi:10.1134/S0036024410070058
(2010)Doi:10.1007/s00706-002-0528-1
(2003)Doi:10.1007/s10562-012-0805-5
(2012)Doi:10.1002/pola.29524
(2019)
