Dioxygenation Reaction of a Cobalt-Nitrosyl: Putative Formation of a Cobalt-Peroxynitrite via a {CoIII(NO)(O2-)} Intermediate

DOI: 10.1021/acs.inorgchem.7b01673

Source and publish data:

Inorganic Chemistry p. 14438 - 14445 (2017)

Update date:2022-08-28

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Authors:

Gogoi, Kuldeep

Saha, Soumen

Mondal, Baishakhi

Deka, Hemanta

Ghosh, Somnath

Mondal, Biplab

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Article abstract of DOI:10.1021/acs.inorgchem.7b01673

A cobalt-nitrosyl complex, [(BPI)Co(NO)(OAc)], 1 {BPI = 1,3-bis(2′-pyridylimino)isoindol} was prepared and characterized. Structural characterization revealed that the cobalt center has a distorted square pyramidal geometry with the NO group coordinated f

Full text of DOI:10.1021/acs.inorgchem.7b01673

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