SELECTIVITY IN ALLYLIC SUBSTITUTIONS WITH ORGANOMETALLICS THROUGH NEIGHBOURING COORDINATION. SYNTHESIS AND REACTIONS OF COPPER(I) ?-COMPLEXES WITH 2-ALLYLLOXYBENZOTHIAZOLES

DOI: 10.1016/S0022-328X(00)81957-9

Source and publish data:

Journal of Organometallic Chemistry p. 179 - 184 (1982)

Update date:2022-08-17

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Authors:

Calo, Vincenzo

Lopez, Luigi

Pesce, Giannangelo

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Article abstract of DOI:10.1016/S0022-328X(00)81957-9

2-Allylloxybenzothiazoles react with CuBr to give stable Cu^I ?-complexes.These complexes undergo nucleophilic attack by organomagnesium compounds to give olefins with very high regio- and stereo-specificity.

Full text of DOI:10.1016/S0022-328X(00)81957-9

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