Journal of Physical Chemistry p. 4478 - 4485 (1992)
Update date:2022-08-17
Topics:
Seakins, Paul W.
Leone, Stephen R.
The reaction of CH3 radicals and O atoms is studied using laser flash photolysis/time resolved Fourier transform infrared emmision spectroscopy.In addition to observing formaldehyde vibrational CH emission, molecular CO vibrational emmission is also detected.Experiments are performed to confirm that CO is a primary product from the title reaction.The observed CO vibrational distributions (ν = 1-8) can be fit with a vibrational temperature of 12700 +/- 1400 K, and the fraction of the reaction exothermicity released into CO vibration is 0.22.The branching fraction to CO is estimated to be 0.40 +/- 0.10.
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