Tetrahedron Letters p. 2995 - 2996 (1982)
Update date:2022-08-16
Topics:
Cesarotti, E.
Chiesa, A.
D'Alfonso, G.
The ligands (S)-N-(diphenylphosphino)-2-diphenylphosphinomethylpyrrolidine, (S)-prolophos, and (S)-1-diphenylphosphinoxy-2-N-ethyl-N-diphenylphosphinoaminobutane,(S)-butaphos, have been prepared.The Rh(I) complexes of these phosphines act as an efficient homogenous hydrogenation catalysts at ambient temperature and pressure for α-N-acetaminoacrylic acid and itaconic acid.
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