EVIDENCE FOR THE EXISTENCE OF PEROXONIUM INTERMEDIATES

DOI: 10.1016/0040-4039(84)80127-6

Source and publish data:

Tetrahedron Letters p. 3769 - 3772 (1984)

Update date:2022-08-22

Topics:

Authors:

Mitchell, John C.

Heaton, Simon

Porter, Ned A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(84)80127-6

Low temperature ¹H and ²H nmr are consistent with the presence of peroxonium intermediates in the intramolecular alkylation of two different bromoperoxides.In one case decomposition of this peroxonium intermediate results in unusual heterolytic oxygen-oxygen bond cleavage and methyl migration.

Full text of DOI:10.1016/0040-4039(84)80127-6

Products guided by the article

Product name:1,8-Bis(bromomethyl)naphthalene

Cas No:2025-95-8

R&D Labs maybe for 2025-95-8

Geen Chemical Technology Co., Ltd

Contact:86-769-21660847

Address:1408, Yingfeng Commercial Center, Nancheng District
ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town
Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
Shenzhen HwaGen Pharmaceutical Co., Ltd

website:http://www.rafflespt.com

Contact:+86-752-5538396

Address:Guangdong Huizhou China
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307

Relevant to this article

Synthesis of acetonides from epoxides catalyzed by erbium(III) triflate

Doi:10.1002/adsc.200505096
(2005)
Doi:10.1002/hlca.19570400408
(1957)
Cobalt(III) polyamine complexes as catalysts for the hydrolysis of phosphate esters and of DNA. A measurable 10 million-fold rate increase

Doi:10.1021/ja964319o
(1997)
Doi:10.1021/ja01590a002
(1956)
Structure-property relationship of 3-(4-substituted benzyl)-1,3-diazaspiro[4.4]nonane-2,4-diones as new potentional anticonvulsant agents. An experimental and theoretical study

Doi:10.1016/j.molstruc.2016.07.069
(2017)
Suprafacial and antarafacial paths for the thermal vinylcyclopropane- to-cyclopentene rearrangement of 1-ethenylbicyclo[4.1.0]heptane to bicyclo[4.3.0]non-1(9)-ene

Doi:10.1021/jo9824091
(1999)

Article Doi